Bis(butylammonium) formamidinium lead iodide

Chemical Formula: (C4H9NH3)2[CH(NH2)2PbI3]PbI4
IUPAC: bis(butane-1-aminium) diaminomethanide lead iodide
Alternate Names: (BA)2[FAPbI3]PbI4, (BA)2(FA)Pb2I7, bis(butane-1-aminium) diaminomethanide tetraiodoplumbate(II)
Organic: C4H12N, CH5N2
Inorganic: Lead iodide
Dimensionality: 2.5D n: 2
Formal Stoichiometry: C : 9 , H : 29 , N : 4 , Pb : 2 , I : 7
Photoluminescence Verified

See all entries for this property (3 total)

Origin: experimental (T = 298.0 K)
L. G. Bonato, J. C. Germino, W. X. Coelho Oliveira, R. Kamat, J. Xu, C. J. Tassone, S. D. Stranks, M. F. Toney, and A. F. Nogueira, Synthesis of Polycrystalline Ruddlesden–Popper Organic Lead Halides and Their Growth Dynamics, Chemistry of Materials 31, 9472‑9479 (2019). doi: 10.1021/acs.chemmater.9b03439.
System description
Dimensionality: 2.5D n: 2
Sample type: powder

Starting materials: PbI2, toluene, butyric acid, butylamine, formamidinium acetate

Product: Powder film on glass substrate

Description: PbI2, toluene, butyric acid, and butylamine were mixed in a capped flask. Separately, formamidinium acetate was dissolved in toluene and butyric acid. The solutions are combined and stirred until a red solid precipitated. The solid was removed by centrifuging at 6000 rpm for 3 minutes. It was then re-dispersed in hexane and centrifuged again to obtain the final paintlike paste. The paintlike paste was then deposited on a glass substrate. A Pasteur pipette was used to spread the paste over the surface and was then allowed to dry.

Method: Photoluminescence Spectra

Description: A Horiba-Jobin Yvon Fluorolog-3 instrument was used on the films to measure photoluminescence spectra. Excitation was perpendicular to the film and emission was collected at an angle of ~15 degrees. The data was corrected according to the lamp and detector details by using algorithms from the equipment software.

L. G. Bonato, J. C. Germino, W. X. Coelho Oliveira, R. Kamat, J. Xu, C. J. Tassone, S. D. Stranks, M. F. Toney, and A. F. Nogueira, Synthesis of Polycrystalline Ruddlesden–Popper Organic Lead Halides and Their Growth Dynamics, Chemistry of Materials 31, 9472‑9479 (2019). doi: 10.1021/acs.chemmater.9b03439.

Extraction method: Engauge digitizer
Entry added on: June 23, 2020, 3:03 p.m.
Entry added by: Andrew Levin NREL
Last updated on: April 7, 2022, 1:06 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

Download data
Data set ID: 954 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!

Absorption spectrum Verified

See all entries for this property (3 total)

Origin: experimental (T = 298.0 K)
L. G. Bonato, J. C. Germino, W. X. Coelho Oliveira, R. Kamat, J. Xu, C. J. Tassone, S. D. Stranks, M. F. Toney, and A. F. Nogueira, Synthesis of Polycrystalline Ruddlesden–Popper Organic Lead Halides and Their Growth Dynamics, Chemistry of Materials 31, 9472‑9479 (2019). doi: 10.1021/acs.chemmater.9b03439.
System description
Dimensionality: 2.5D n: 2
Sample type: powder

Starting materials: PbI2, toluene, butyric acid, butylamine, formamidinium acetate

Product: Powder film on glass substrate

Description: PbI2, toluene, butyric acid, and butylamine were mixed in a capped flask. Separately, formamidinium acetate was dissolved in toluene and butyric acid. The solutions are combined and stirred until a red solid precipitated. The solid was removed by centrifuging at 6000 rpm for 3 minutes. It was then re-dispersed in hexane and centrifuged again to obtain the final paintlike paste. The paintlike paste was then deposited on a glass substrate. A Pasteur pipette was used to spread the paste over the surface and was then allowed to dry.

Method: Diffuse Reflectance Spectra

Description: Diffuse reflectance spectra were measured in a Shimadzu UV 2450 instrument. A Ba2SO4 powder palette was the reference used.

L. G. Bonato, J. C. Germino, W. X. Coelho Oliveira, R. Kamat, J. Xu, C. J. Tassone, S. D. Stranks, M. F. Toney, and A. F. Nogueira, Synthesis of Polycrystalline Ruddlesden–Popper Organic Lead Halides and Their Growth Dynamics, Chemistry of Materials 31, 9472‑9479 (2019). doi: 10.1021/acs.chemmater.9b03439.

Extraction method: Engauge digitizer
Entry added on: June 23, 2020, 3:16 p.m.
Entry added by: Andrew Levin NREL
Last updated on: April 7, 2022, 1:12 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

Download data
Data set ID: 956 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!


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