Formamidinium lead bromide

Chemical Formula: CH5N2PbBr3
IUPAC: Imidoformamidinium lead(II) bromide
Alternate Names: Methanimidamide tribromoplumbate(II), FAPBr3, FAPBr, (FA)PbBr3 HC(NH2)2PbBr3, (NH2)2CHPbBr3
Organic: CH5N2
Inorganic: PbBr3, Lead bromide
Dimensionality: 3D
Formal Stoichiometry: C : 1 , H : 5 , N : 2 , Pb : 1 , Br : 3
Absorption spectrum
Origin: experimental
S. Kumar, J. Jagielski, N. Kallikounis, Y. Kim, C. Wolf, F. Jenny, T. Tian, C. J. Hofer, Y. Chiu, W. J. Stark, T. Lee, and C. Shih, Ultrapure Green Light-Emitting Diodes Using Two-Dimensional Formamidinium Perovskites: Achieving Recommendation 2020 Color Coordinates, Nano Letters 9, 5277‑5284 (2017). doi: https://doi.org/10.1021/acs.nanolett.7b01544.
System description
Dimensionality: 3D
Sample type: single crystal

Starting materials: FABr (0.53M), PbBr2 (0.4 M), Ethanol, OLA (625 μL), OA (25 μL), (Toluene, 12.5 mL

Product: FAPbBr3

Description: The 2D perovskite FAPbBr3 was synthesized from a solution that included FABr ( 625 μL)dissolved in a non-polar toluene solvent and a polar Ethanol solvent. The nonpolar solvent contained OA and OLA as organic surfactants, which stabilized the solutions. As a result, a precipitate of the solution formed from the poor solubility of perovskites in the nonpolar solvent. This yielded the final product of FAPbBr3 nanoplatelets in 2.5 mL of Toluene, which was then dissolved in ethanol (375 μL) to produce higher and more stable concentrations of FAPbBr3 nanoplatelet.

Method: Photoluminescence Spectra

Description: A CCD spectrometer was used to obtain the absolute absorbance of the colloidal solution in the non-polar solvent of Toluene. The PL of the colloidal solutions were obtained using the Quantaurus QY (C11347-11) from Hamamatsu.

S. Kumar, J. Jagielski, N. Kallikounis, Y. Kim, C. Wolf, F. Jenny, T. Tian, C. J. Hofer, Y. Chiu, W. J. Stark, T. Lee, and C. Shih, Ultrapure Green Light-Emitting Diodes Using Two-Dimensional Formamidinium Perovskites: Achieving Recommendation 2020 Color Coordinates, Nano Letters 9, 5277‑5284 (2017). doi: https://doi.org/10.1021/acs.nanolett.7b01544.

Extraction method: Engauge Digitizer
Entry added on: Aug. 21, 2020, 1:23 p.m.
Entry added by: Lily Al-Omari University of North Carolina at Chapel Hill (Undergraduate)
Last updated on: April 21, 2022, 12:54 p.m.
Last updated by: Rayan C Duke University

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