Crystal system: monoclinic
| a: | 17.055 (±0.0006) Å |
| b: | 10.0193 (±0.0003) Å |
| c: | 37.8344 (±0.0014) Å |
| α: | 90° |
| β: | 101.131 (±0.004)° |
| γ: | 90° |
Starting materials: SnBr2, hydrobromic acid, phenylethylamine, ethanol, DMF, CH3CN
Product: colorless crystals
Description: Hydrobromic acid solution (1.74 mL, 15.4 mmol) was added in 100 mL of ethanol. White organic salts were obtained after filtration under vacuum, then washed and dried. SnBr2 (2.0 mmol) was dissolved with PEABr (8.0 mmol) with 1 mL of DMF and 2 mL CH3CN. Colorless block crystals formed after the vial was left to stand for 3 days.
Method: Single crystal X-ray diffraction
Description: SCXRD data collected using a Rigaku XtaLAB Synergy-S diffractometer equipped wtih a HyPix-6000HE Hybrid Photon Counting detector.