See all entries for this property (2 total)
Crystal system: orthorhombic
| a: | 9.1437 (±0.0002) Å |
| b: | 8.6684 (±0.0002) Å |
| c: | 28.5984 (±0.0005) Å |
| α: | 90° |
| β: | 90° |
| γ: | 90° |
Starting materials: Benzylamine (BzA), PbI2, Aq. HI (57%), H3PO2 (50 %)
Product: Orange (BzA)2PbI4 crystals
Description: BzA (214.45 mg) was dissolved in Aq.HI (4.5 ml) treated with hypophosphorous acid (0.5 ml) as a stabilizer. A stoichiometric amount of PbI2 (461.01) was added to the above solution, stirred at 90 °C for 2 h, and cooled to room temperature at a rate of 1 K/hr to induce crystallization. All synthesis was performed at ambient conditions. The as-formed crystals were collected by suction, washed with diethyl ether and dried under vacuum.
Method: single crystal X-ray diffraction
Description: Single crystal X-ray data were collected on a Nonius Kappa CCD single-crystal diffractometer (MoKα, λ = 0.71073 Å) at 180 K.