Crystal system: orthorhombic
| a: | 8.1 (±0.0003) Å |
| b: | 8.4632 (±0.0003) Å |
| c: | 25.3124 (±0.0009) Å |
| α: | 90° |
| β: | 90° |
| γ: | 90° |
Starting materials: (S)-(−)-1-(1-naphthyl)ethylamine (≥99%), PbI2
Product: S-NEA2Pb2I6 (S-NPI)
Description: Single crystals of 1D S-NEA2Pb2I6 (S-NPI) were obtained by cooling a hot aq. HI solution of S-1-(1-naphthyl)ethylamine (0.25 mmol) and PbI2 (0.125 mmol) from 90 °C to room-temperature in 48 hr. The pale-yellow, needle-like crystals were filtered, washed with diethyl ether, and vacuum-dried.
Method: Single crystal X-ray diffraction
Description: Single crystal X-ray diffraction (XRD) was performed at 298 K on a Bruker APEX II CCD diffractometer using Mo-Kα radiation (λ=0.710 Å) and X-ray tube operating at 50 kV and 30 mA