Methylammonium lead bromide: phase transition temperature

Phase transition temperature Verified
Origin: experimental
Phase transition #1 - 144.5-149.5
Initial crystal system orthorhombic
Final crystal system tetragonal
Initial space group Pna2_1
Final space group P4/mmm
Direction Unknown
Phase transition temperature 144.5 K

Hysteresis: NIL

A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
Phase transition #2
Initial crystal system tetragonal
Final crystal system tetragonal
Initial space group P4/mmm
Final space group I4/mcm
Direction Unknown
Phase transition temperature 155.1 K

Hysteresis: NIL

A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
Phase transition #3
Initial crystal system tetragonal
Final crystal system cubic
Initial space group I4/mcm
Final space group Pm3m
Direction Unknown
Phase transition temperature 236.9 K

Hysteresis: NIL

A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
System description
Dimensionality: 3D
Sample type: powder

Starting materials: lead (II) acetate, CH3NH3+ (by adding a 40% solution of CH3NH2 in water), concentrated HBr

Product: Orange MAPbBr3 crystals

Description: CH3NH3PbBr3 was synthesized from lead (II) acetate and CH3NH3+ dissolved in concentrated HBr solution. The aqueous solution was cooled from l00°C to room temperature to obtain the orange crystals.

Method: Temperature-dependent Guinier-Simon photograph

Description: No method specified. Refer to Page 6374 Table I.

A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.

Entry added on: June 18, 2019, 11:50 a.m.
Entry added by: Xiaochen Du Duke University
Last updated on: March 29, 2022, 1:59 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

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