A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
Methylammonium lead chloride: atomic structure Verified

See all entries for this property (7 total)

Origin: experimental (T = >178.8 K)
Space group: Pm3m
Lattice parameters

Crystal system: cubic

a:5.675 Å
b:5.675 Å
c:5.675 Å
α:90°
β:90°
γ:90°
Fixed parameters:
  • temperature = >178.8 K
A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
System description
Dimensionality: D
Sample type: powder

Starting materials: lead (II) acetate, CH3NH3+ (by adding a 40% solution of CH3NH2 in water), concentrated HCl

Product: Colorless MAPbCl3 crystals

Description: CH3NH3PbCI3 was synthesized from lead (II) acetate and CH3NH3+ dissolved in concentrated HCl solution. The aqueous solution was cooled from l00°C to room temperature to obtain the colorless crystals.

Method: Temperature-dependent Guinier-Simon photograph

Description: Not specified.

Extraction method: Manual entry
Entry added on: April 8, 2019, 5:05 p.m.
Entry added by: Xiaochen Du Duke University
Last updated on: March 29, 2022, 2:03 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

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Data set ID: 166 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!

Methylammonium lead chloride: atomic structure Verified

See all entries for this property (7 total)

Origin: experimental
Space group: P 4/m m m
Lattice parameters

Crystal system: tetragonal

a:5.656 Å
b:5.656 Å
c:5.63 Å
α:90°
β:90°
γ:90°
Fixed parameters:
  • atomic structure = >172.9 K
  • atomic structure = <178.8 K
A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
System description
Dimensionality: D
Sample type: powder

Starting materials: lead (II) acetate, CH3NH3+ (by adding a 40% solution of CH3NH2 in water), concentrated HCl

Product: Colorless MAPbCl3 crystals

Description: CH3NH3PbCI3 was synthesized from lead (II) acetate and CH3NH3+ dissolved in concentrated HCl solution. The aqueous solution was cooled from l00°C to room temperature to obtain the colorless crystals.

Method: Temperature-dependent Guinier-Simon photograph

Description: Not specified.

Extraction method: Manual entry
Entry added on: April 8, 2019, 5:11 p.m.
Entry added by: Xiaochen Du Duke University
Last updated on: June 22, 2022, 10:05 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

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Data set ID: 167 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!

Methylammonium lead chloride: atomic structure Verified

See all entries for this property (7 total)

Origin: experimental (T = <172.9 K)
Space group: P 2 2 2₁
Lattice parameters

Crystal system: orthorhombic

a:5.673 Å
b:5.628 Å
c:11.182 Å
α:90°
β:90°
γ:90°
Fixed parameters:
  • temperature = <172.9 K
A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
System description
Dimensionality: D
Sample type: powder

Starting materials: lead (II) acetate, CH3NH3+ (by adding a 40% solution of CH3NH2 in water), concentrated HCl

Product: Colorless MAPbCl3 crystals

Description: CH3NH3PbCI3 was synthesized from lead (II) acetate and CH3NH3+ dissolved in concentrated HCl solution. The aqueous solution was cooled from l00°C to room temperature to obtain the colorless crystals.

Method: Temperature-dependent Guinier-Simon photograph

Description: Not specified.

Extraction method: Manual entry
Entry added on: April 8, 2019, 5:15 p.m.
Entry added by: Xiaochen Du Duke University
Last updated on: June 22, 2022, 10:05 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

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Data set ID: 168 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!

Methylammonium lead bromide: atomic structure Verified

See all entries for this property (24 total)

Origin: experimental (T = >236.9 K)
Space group: Pm3m
Lattice parameters

Crystal system: cubic

a:5.901 (±0.001) Å
b:5.901 (±0.001) Å
c:5.901 (±0.001) Å
α:90°
β:90°
γ:90°
Fixed parameters:
  • temperature = >236.9 K
A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
System description
Dimensionality: D
Sample type: powder

Starting materials: lead (II) acetate, CH3NH3+ (by adding a 40% solution of CH3NH2 in water), concentrated HBr

Product: Orange MAPbBr3 crystals

Description: CH3NH3PbBr3 was synthesized from lead (II) acetate and CH3NH3+ dissolved in concentrated HBr solution. The aqueous solution was cooled from l00°C to room temperature to obtain the orange crystals.

Method: temperature-dependent Guinier-Simon photograph

Description: No experimental details reported. Refer to Page 6374 Table I.

Extraction method: manual entry
Entry added on: April 22, 2019, 1:26 p.m.
Entry added by: Xiaochen Du Duke University
Last updated on: March 29, 2022, 2:07 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

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Data set ID: 265 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!

Methylammonium lead bromide: atomic structure Verified

See all entries for this property (24 total)

Origin: experimental (T = >155.1 K, <236.9 K)
Space group: I 4/m c m
Lattice parameters

Crystal system: tetragonal

a:8.322 (±0.002) Å
b:8.322 (±0.002) Å
c:11.832 (±0.007) Å
α:90°
β:90°
γ:90°
Fixed parameters:
  • temperature = >155.1 K
  • temperature = <236.9 K
A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
System description
Dimensionality: D
Sample type: powder

Starting materials: lead (II) acetate, CH3NH3+ (by adding a 40% solution of CH3NH2 in water), concentrated HBr

Product: Orange MAPbBr3 crystals

Description: CH3NH3PbBr3 was synthesized from lead (II) acetate and CH3NH3+ dissolved in concentrated HBr solution. The aqueous solution was cooled from l00°C to room temperature to obtain the orange crystals.

Method: temperature-dependent Guinier-Simon photograph

Description: No experimental details reported. Refer to Page 6374 Table I.

Extraction method: Manual entry
Entry added on: April 22, 2019, 1:32 p.m.
Entry added by: Xiaochen Du Duke University
Last updated on: June 22, 2022, 10:11 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

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Data set ID: 266 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!

Methylammonium lead bromide: atomic structure Verified

See all entries for this property (24 total)

Origin: experimental (T = >149.5 K, <155.1 K)
Space group: P 4/m m m
Lattice parameters

Crystal system: tetragonal

a:5.894 (±0.002) Å
b:5.894 (±0.002) Å
c:5.861 (±0.002) Å
α:90°
β:90°
γ:90°
Fixed parameters:
  • temperature = >149.5 K
  • temperature = <155.1 K
A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
System description
Dimensionality: D
Sample type: powder

Starting materials: lead (II) acetate, CH3NH3+ (by adding a 40% solution of CH3NH2 in water), concentrated HBr

Product: Orange MAPbBr3 crystals

Description: CH3NH3PbBr3 was synthesized from lead (II) acetate and CH3NH3+ dissolved in concentrated HBr solution. The aqueous solution was cooled from l00°C to room temperature to obtain the orange crystals.

Method: temperature-dependent Guinier-Simon photograph

Description: No experimental details reported. Refer to Page 6374 Table I.

Extraction method: manual entry
Entry added on: April 22, 2019, 1:35 p.m.
Entry added by: Xiaochen Du Duke University
Last updated on: June 22, 2022, 10:11 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

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Data set ID: 267 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!

Methylammonium lead bromide: atomic structure Verified

See all entries for this property (24 total)

Origin: experimental (T = <144.5 K)
Space group: P n a 2₁
Lattice parameters

Crystal system: orthorhombic

a:7.979 (±0.001) Å
b:8.58 (±0.002) Å
c:11.849 (±0.002) Å
α:90°
β:90°
γ:90°
Fixed parameters:
  • temperature = <144.5 K
A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
System description
Dimensionality: D
Sample type: powder

Starting materials: lead (II) acetate, CH3NH3+ (by adding a 40% solution of CH3NH2 in water), concentrated HBr

Product: Orange MAPbBr3 crystals

Description: CH3NH3PbBr3 was synthesized from lead (II) acetate and CH3NH3+ dissolved in concentrated HBr solution. The aqueous solution was cooled from l00°C to room temperature to obtain the orange crystals.

Method: temperature-dependent Guinier-Simon photograph

Description: No experimental details reported. Refer to Page 6374 Table I.

Extraction method: manual entry
Entry added on: April 22, 2019, 1:38 p.m.
Entry added by: Xiaochen Du Duke University
Last updated on: June 22, 2022, 10:11 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

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Data set ID: 268 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!

Methylammonium lead iodide: atomic structure Verified

See all entries for this property (35 total)

Origin: experimental (T = >327.4 K)
Space group: Pm3m
Lattice parameters

Crystal system: cubic

a:6.3285 (±0.0004) Å
b:6.3285 (±0.0004) Å
c:6.3285 (±0.0004) Å
α:90°
β:90°
γ:90°
Fixed parameters:
  • temperature = >327.4 K
A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
System description
Dimensionality: D
Sample type: powder

Starting materials: lead (II) acetate, CH3NH3+ (by adding a 40% solution of CH3NH2 in water), concentrated HI

Product: Black MAPbI3 crystals

Description: CH3NH3PbI3 was synthesized from lead (II) acetate and CH3NH3+ dissolved in a concentrated HI solution. The aqueous solution was cooled from l00°C to 40°C to obtain the black crystals.

Method: temperature-dependent Guinier-Simon photograph

Description: No experimental details reported. Refer to Page 6374 Table I.

Extraction method: manual entry
Entry added on: April 22, 2019, 1:41 p.m.
Entry added by: Xiaochen Du Duke University
Last updated on: March 29, 2022, 2:11 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

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Data set ID: 269 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!

Methylammonium lead iodide: atomic structure Verified

See all entries for this property (35 total)

Origin: experimental (T = >162.2 K, <327.4 K)
Space group: I 4/m c m
Lattice parameters

Crystal system: tetragonal

a:8.855 (±0.006) Å
b:8.855 (±0.006) Å
c:12.659 (±0.008) Å
α:90°
β:90°
γ:90°
Fixed parameters:
  • temperature = >162.2 K
  • temperature = <327.4 K
A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
System description
Dimensionality: D
Sample type: powder

Starting materials: lead (II) acetate, CH3NH3+ (by adding a 40% solution of CH3NH2 in water), concentrated HI

Product: Black MAPbI3 crystals

Description: CH3NH3PbI3 was synthesized from lead (II) acetate and CH3NH3+ dissolved in a concentrated HI solution. The aqueous solution was cooled from l00°C to 40°C to obtain the black crystals.

Method: temperature-dependent Guinier-Simon photograph

Description: No experimental details reported. Refer to Page 6374 Table I.

Extraction method: manual entry
Entry added on: April 22, 2019, 1:44 p.m.
Entry added by: Xiaochen Du Duke University
Last updated on: June 22, 2022, 10:10 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

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Data set ID: 270 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!

Methylammonium lead iodide: atomic structure Verified

See all entries for this property (35 total)

Origin: experimental (T = <162.2 K)
Space group: P n a 2₁
Lattice parameters

Crystal system: orthorhombic

a:8.861 (±0.002) Å
b:8.581 (±0.002) Å
c:12.62 (±0.003) Å
α:90°
β:90°
γ:90°
Fixed parameters:
  • temperature = <162.2 K
A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
System description
Dimensionality: D
Sample type: powder

Starting materials: lead (II) acetate, CH3NH3+ (by adding a 40% solution of CH3NH2 in water), concentrated HI

Product: Black MAPbI3 crystals

Description: CH3NH3PbI3 was synthesized from lead (II) acetate and CH3NH3+ dissolved in a concentrated HI solution. The aqueous solution was cooled from l00°C to 40°C to obtain the black crystals.

Method: temperature-dependent Guinier-Simon photograph

Description: No experimental details reported. Refer to Page 6374 Table I.

Extraction method: manual entry
Entry added on: April 22, 2019, 1:47 p.m.
Entry added by: Xiaochen Du Duke University
Last updated on: June 22, 2022, 10:10 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

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Data set ID: 271 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!

Methylammonium lead chloride: phase transition temperature Verified

See all entries for this property (5 total)

Origin: experimental
Phase transition #1
Initial crystal system orthorhombic
Final crystal system tetragonal
Initial space group P222_1
Final space group P4/mmm
Direction Unknown
Phase transition temperature 172.9 K

Hysteresis: NIL

A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
Phase transition #2
Initial crystal system tetragonal
Final crystal system cubic
Initial space group P4/mmm
Final space group Pm3m
Direction Unknown
Phase transition temperature 178.8 K

Hysteresis: NIL

A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
System description
Dimensionality: D
Sample type: powder

Starting materials: lead (II) acetate, CH3NH3+ (by adding a 40% solution of CH3NH2 in water), concentrated HCl

Product: Colorless MAPbCl3 crystals

Description: CH3NH3PbCI3 was synthesized from lead (II) acetate and CH3NH3+ dissolved in concentrated HCl solution. The aqueous solution was cooled from l00°C to room temperature to obtain the colorless crystals.

Method: Temperature-dependent Guinier-Simon photograph

Description: No method specified. Refer to Page 6374 Table I.

Entry added on: June 18, 2019, 11:41 a.m.
Entry added by: Xiaochen Du Duke University
Last updated on: March 29, 2022, 1:55 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

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Data set ID: 446 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!

Methylammonium lead bromide: phase transition temperature Verified

See all entries for this property (6 total)

Origin: experimental
Phase transition #1 - 144.5-149.5
Initial crystal system orthorhombic
Final crystal system tetragonal
Initial space group Pna2_1
Final space group P4/mmm
Direction Unknown
Phase transition temperature 144.5 K

Hysteresis: NIL

A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
Phase transition #2
Initial crystal system tetragonal
Final crystal system tetragonal
Initial space group P4/mmm
Final space group I4/mcm
Direction Unknown
Phase transition temperature 155.1 K

Hysteresis: NIL

A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
Phase transition #3
Initial crystal system tetragonal
Final crystal system cubic
Initial space group I4/mcm
Final space group Pm3m
Direction Unknown
Phase transition temperature 236.9 K

Hysteresis: NIL

A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
System description
Dimensionality: D
Sample type: powder

Starting materials: lead (II) acetate, CH3NH3+ (by adding a 40% solution of CH3NH2 in water), concentrated HBr

Product: Orange MAPbBr3 crystals

Description: CH3NH3PbBr3 was synthesized from lead (II) acetate and CH3NH3+ dissolved in concentrated HBr solution. The aqueous solution was cooled from l00°C to room temperature to obtain the orange crystals.

Method: Temperature-dependent Guinier-Simon photograph

Description: No method specified. Refer to Page 6374 Table I.

Entry added on: June 18, 2019, 11:50 a.m.
Entry added by: Xiaochen Du Duke University
Last updated on: March 29, 2022, 1:59 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

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Data set ID: 448 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!

Methylammonium lead iodide: phase transition temperature Verified

See all entries for this property (20 total)

Origin: experimental
Phase transition #1
Initial crystal system orthorhombic
Final crystal system tetragonal
Initial space group Pna2_1
Final space group I4/mcm
Direction Unknown
Phase transition temperature 162.2 K

Hysteresis: NIL

A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
Phase transition #2
Initial crystal system tetragonal
Final crystal system cubic
Initial space group I4/mcm
Final space group Pm3m
Direction Unknown
Phase transition temperature 327.4 K

Hysteresis: NIL

A. Poglitsch and D. Weber, Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy, The Journal of Chemical Physics 87, 6373‑6378 (1987). doi: 10.1063/1.453467.
System description
Dimensionality: D
Sample type: powder

Starting materials: lead (II) acetate, CH3NH3+ (by adding a 40% solution of CH3NH2 in water), concentrated HI

Product: Black MAPbI3 crystals

Description: CH3NH3PbI3 was synthesized from lead (II) acetate and CH3NH3+ dissolved in a concentrated HI solution. The aqueous solution was cooled from l00°C to 40°C to obtain the black crystals.

Method: Temperature-dependent Guinier-Simon photograph

Description: No method specified. Refer to Page 6374 Table I.

Entry added on: June 18, 2019, 11:54 a.m.
Entry added by: Xiaochen Du Duke University
Last updated on: March 29, 2022, 2 p.m.
Last updated by: Rayan C Duke University
Data correctness verified by:
  • Rayan C Duke University

Download data
Data set ID: 449 Did you find any mistakes or inconsistencies about this data? Send us a note and we'll have a look at it and send you a reply. Thanks!


License

All data is available under the Creative Commons license with attribution clause, described here and, in its full text, here.